There were some questions asked the other day regarding using VMware Convertor and whether it performs a disk alignment when performing a P2V.
The answer is NO. VMware Convertor doesn’t do any disk alignment. You will need to carry out the alignment manually afterwards.
I have listed some good links covering disk alignment and how to perform this task.
http://communities.vmware.com/message/1184316
http://www.yellow-bricks.com/2009/01/17/check-your-vms-alignment/
One other great resource that Steve Chambers and I worked on about this -> http://communities.vmware.com/docs/DOC-11458
Dave